The luminescent safety vests composes of several pairs of photoluminescent layer and reflective layer from inside out, and can both radiate and reflect light. And when it is in darkness, it will radiate light to give safety indication and warning. The belt can be sewn on garments directly and connected with other objects in an easy way. The photoluminescent reflective tape exists in laminated structure, When there is light shot onto the belt, it will reflect strong light. Whatever there is a light source or not, the vests can be visible at nighttime. That is suitable for use on working at high way, work for fire protection department, police department, and architecture workers.